One-photon and Two-photon Electronic Spectra of Two Caged Amines

Photon-added one-photon and two-photon nonlinear coherent states

From the photon-added one-photon nonlinear coherent states a†m|α, f〉, we introduce a new type of nonlinear coherent states with negative values of m. The nonlinear coherent states corresponding to the positive and negative values of m are shown to be the result of nonunitarily deforming the number states |m〉 and |0〉, respectively. As an example, we study the sub-Poissonian statistics and squeez...

Two-photon absorption spectra of carotenoids compounds

Quantum effects in one-photon and two-photon interference

Although interference is intrinsically a classical wave phenomenon, the superposition principle which underlies all interference is also at the heart of quantum mechanics. Feynman has referred to interference as really ‘‘the only mystery’’ of quantum mechanics. Furthermore, in some interference experiments we encounter the idea of quantum entanglement, which has also been described as really th...

Fano profiles in two-photon photoassociation spectra.

In this article we derive the lineshapes observed in two-photon photoassociation spectrocopy of molecules using an effective Hamiltonian adapted from previous work in atomic physics. The lineshape is decomposed in terms of sums and products of Breit-Wigner and Fano profiles, which we associate with physical absorption and emission processes, and to quantum interferences between transition ampli...

Synthesis of a caged glutamate for efficient one- and two-photon photorelease on living cells.

We have synthesized a biologically inert, photosensitive derivative of the major excitatory amino acid, L-glutamate (which we call MDNI-glu) that makes more efficient use of incident light than all other caged glutamates. Laser flash photolysis of MDNI-glu in acutely isolated hippocampal brain slices evoked a rapid increase in intracellular Ca2+ concentration in astrocytes.